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Beilstein J. Org. Chem. 2020, 16, 1277–1287, doi:10.3762/bjoc.16.108
Graphical Abstract
Figure 1: Previously reported antiinflammatory bisphosphonates 1 and 2. edema inhibition (in %, carrageenan m...
Figure 2: Designed bisphosphonic esters as antiinflammatory agents.
Scheme 1: Synthesis of the intermediate bromoaceto esters 7–10.
Scheme 2: Synthesis of the bisphosphonates 3–6.
Figure 3: Coordination of the Zn2+ ion by residues and by the carbonyl ester oxygen atom of molecule 3. The b...
Figure 4: 2D schematic representations of the MMP-8 catalytic site, with 3–6 and the most relevant interactio...
Figure 5: 2D schematic representations of the MMP-9 catalytic site, with 3–6 and the most relevant interactio...